This appendix is intended for facilities with ammonia. Iiar process safety management guidelines for ammonia refrigeration. Intended use of the product uses of the substancemixture. Risk management rmp and process safety management psm. The standard ph of ammonia explains many of the properties of the chemical. Gcap ammonia psmrmp program activities provided as a training example only this document summarizes how gcap complies with the requirements of the occupational safety and health administrations osha process safety management of highly hazardous chemicals regulation at 29 cfr 1910. Sam mannan source term modeling is the key feature in predicting the consequences of releases from hazardous fluids. We believe that sharing knowledge by constant publishing of relevant articles can enhance the ammonia process safety management ammonia psm awareness and contribute to ammonia and urea industry employees working together to identify the root causes of accidents, minimizing risks and prevent incidents from repeating. This odor is very recognizable because ammonia is used in the creation of smelling salts, household and industrial cleaners, and glass cleaners, so we come in contact with it almost every day. Psm software online service and maintenance application for process safety. Hot air vaporizers use an evaporativetype vaporizer with internal air atomizing nozzles.
With 27 distribution facilities nationwide, airgas specialty products has the ability to meet your delivery needs for industrial ammonia. Ammonia, as a gas or in aqueous solution is an irritant and corrosive to the skin, eyes, respiratory tract and mucous membranes. Both the rescinded memorandum and its replacement memorandum state that there are 11 chemicals to which this exception applies, without listing the chemicals. Exhibit 21 provides a summary of the criteria for determining program level. Ammonia is a common liquid used in households and industry, easily identified by its distinctive smell. Che5042s 29 p270 do not eat, drink or smoke when using this product. Household strength aqua ammonia is primarily used with other. Bringing together leaders from industry and public safety organizations with hundreds of years of combined experience, asti provides safety management support. Ammonia refrigeration iiar process safety management. Tech, university of madras chair of advisory committee. Ammonium hydroxide solutions, aqua ammonia, aqua ammonia solutions, ammonia solutions, ammonia aqueous, ammonia water cas registry no. We offer customized service contracts to fit your companys specific needs for ongoing compliance. Details of the supplier of the safety data sheet pcs sales usa, inc. Ammonia can burn or explode if exposed to an intense source of ignition but can generally be treated as nonflammable.
Garden city ammonia programs psmrmp course ammonia. Ammonia specific psmrmp awareness dvd garden city ammonia program has develeped a 22 minute dvd specifically for psmrmp ammonia awareness. Truly the easiest to use and most unique psm tools on the market. Owner or operator of a stationary source with processes subject to program 2 or program 3 shall develop a management system to oversee the implementation of the risk management program elements 40 cfr 68. Additional guidance on who must report, reportable quantities, and how to estimate annual releases can be found in the following sections. The decomposition temperature may be lowered to 575o f 300o c by contact with certain metals such as nickel. Both the psm standard and epas risk management program are. So 20,000 lbs of 60% aqueous ammonia, which is above the listed concentration for aqueous ammonia of 44 %, will contribute 12,000 lb of ammonia toward the tq. With our equipment, we can oversee everything from o 2 removal prior to the first fill of ammonia, to full commissioning of your systems up to sending ammonia to the aig. The look at a detailed index of the book please visit this link. In addition to supplying you with ammonia, airgas specialty products can provide turnkey solutions for your ammonia storage and handling needs. All of this material is covered or introduced to the student at our seminar. Osha psm a brief overview of osha psm and how it correlates to epas risk management program 1 osha psm 5720.
The sponsorship of these industryleading companies helps us continue our mission to make ammonia nh3 the safest managed hazardous material in the world. Ammonia aqueous, 25% ammonia water ammonia aqueous solution 10% ammonia aqueous solution 5% ammonia aqua. Anhydrous ammonia, aqua ammonia 44% concentration and nitric. It is designed to give new hires a brief idea of the. Aqua ammonia is also known as ammonia solution, ammonium hydroxide, ammonia water, ammonical liquor, ammonia liquor, aqueous ammonia, or simply ammonia. Process safety management psm for ag retailers asmark institute. The purpose of this rmp psm manual is to assist with the prevention of accidental releases of toxic and flammable substances that can cause harm to the public, facility employees, and to the environment. Ammonia refrigeration osha psm citation ammonia psm. Ammonia, aqueous nh 3aq cas no 36216 approximately 30% nh 3 synonyms.
Relevant identified uses of the substance or mixture and uses advised against use of the substancepreparation. Process safety management of highly hazardous chemicals. This selection of material will allow success in companys regulatory requirements. Jeremy williams this last week gcap rehearsed an ammonia leak and trained on how to handle incidental releases and determine when to initiate the emergency action plan andor response. Gcap offers a comprehensive compliance audit for ammonia refrigeration psm rmp programs. Aqua ammonia solubility water and ammonia are miscible in all proportions. Skin and respiratory related diseases are aggravated by exposure. Many of ammonias uses and benefits derive from its ph level, which is the measure of how acidic or alkaline basic a solution is. Tccs aqua ammonia is a clear, colorless liquid with a strong pungent ammonia odor. Oshas definition of flammable is different than epas. Anhydrous ammonia 10,000 10,000 aqueous ammonia 20%, aqueous ammonia 44% 20,000 15,000 chlorine 2,500 1.
Gcaps ammonia psmrmp competencies ammonia training. No organization is situated to provide you with a more thorough process safety management audit than gcap. Resource compliance can also help manage your rmp, psm, or calarp programs. Airgas specialty products will develop a psmrmp program uniquely fitted. Name, address, and telephone of the responsible party company. Psm i for ammonia systems will give you a general understanding of psm and its history to guide the implementation. Also known as ammoniacal liquor, it is an inorganic chemical used as a liquid chemical in various industries like rubber, pharmaceuticals among others.
Ammonia in water, commonly known as aqua ammonia renders it safe to handle and helps avoid the hazards that accompany use of ammonia gas by greatly reducing its vapour pressure. Psm compliance software ammonia refrgeration protexus. In accordance with these letters of interpretation, aqueous hydrochloric acid also known as muriatic acid and aqueous hydrofluoric acid are not covered by the psm standard. This is a suggested method for marking pipe, valves, and system components. Garden city ammonia program gcap ammonia psmrmp program. This is a hefty proposed fine and is one of few that has happen from osha on a psm nh3 covered process. If your ammonia process is not eligible for program 1, it will generally be subject to program 3. Safe handling of anhydrous ammonia power engineering. Anhydrous ammonia in liquid or gaseous form has a very strong attraction to water and moisture which targets bodily fluids such as those in the eyes, nose, mouth, respiratory tract, and perspiration and forms strong concentrations of aqueous ammonia that irritate body tissues and may cause.
Many businesses that use anhydrous ammonia in their operations currently do not have the necessary knowledge base to create and implement an effective process safety management psm program. The escalation process and automated reminders built into the tools ensures you dont go out of compliance. Ammonia refrigeration systems that have 10,000 pounds of ammonia approximately 2,000 gallons or more are subject to oshas process safety management requirements. This document contains information for facilities which manufacture, produce, or otherwise use aqueous ammonia. Rmp guidance for ammonia refrigeration 40 cfr part 68. Osha proposes that the meatpacking facility failed to implement a required process safety management psm program for operating an ammonia refrigeration unit containing over 10,000 pounds of anhydrous ammonia. Identification of ammonia refrigeration piping and system components. When one refers to the solubility of ammonia in water, it is usually meant to be the solubility at a given temperature for which the vapor pressure is equal to atmospheric pressure.
Ammonia nh 3 health effects of exposure to ammonia. It becomes a deep blue color with copper solutions. Storage and delivery systems airgas specialty products ammonia storage tanks and equipment. Psm pro a cloudbased process safety management software program designed specifically for the ammonia refrigeration industry for compliance with osha psm standard 1910. Household strength aqua ammonia is primarily used with other ingredients as a. At 12900 f 6900 c or in the presence of electric spark ammonia decomposes into nitrogen and hydrogen gases, which. Ppe for exposure to liquid anhydrous ammonia or aqueous solutions of. Specifically, this psm standard is applicable to ammonia manufacturers and facilities with large ammonia refrigeration systems. Provides and overview of oshas process safety management psm standard. Tons of steel crash to the earth near minot, nd as a canadian pacific railway freight train derails 31 of its 112 cars. An example of a guideline will be iiar bulletin 114, guideline for. This appendix replaces the former standalone document risk management program guidance for ammonia refrigeration.
Page 1 of 12 1 page 1 of 12 uncontrolled copy if printed. None implementing process safety management for ammonia refrigeration systems 6th edition. This has resulted in many psm accidents, releases, and catastrophes. Ammonia dissolves readily in water to form ammonium hydroxidean alkaline solution. Aqueous ammonia, as its otherwise known is used as a complexant and base in qualitative inorganic analysis. Aqueous ammonia is a safer ammonia reagent for scr applications than anhydrous ammonia. Consequence analysis of aqueous ammonia spills using an improved liquid pool evaporation model. Ammonium hydroxide, also known as aqua ammonia, is a clear, colorless liquid. Hydrogen is released on heating ammonia above 850o f 454o c. Energy procedia 37 20 677 a 682 18766102 a 20 the authors. Implementing process safety management for ammonia refrigeration sixth edition is available june 2018.
Additionally in the case of 19% aqueous ammonia, there will be approximately five times as many deliveries as anhydrous ammonia. Facilities with refrigeration systems over 10,000 pounds of anhydrous ammonia are subject to osha code of federal regulations 29cfr section 1910. We offer a wide array of storage tanks for both anhydrous and aqueous ammonia. Aqueous ammonia 20%, aqueous ammonia, which is above the listed concentration for aqueous ammonia of 44%, will contribute 12,000 lb of ammonia toward the tq. Total vapor pressure of aqua ammonia solutions expressed in pounds absolute. There is a separate entry in appendix a for ammonia solutions 44% ammonia by weight, which covers aqueous ammonia mixtures of greater than 44% concentration. It is a solution of ammonia gas a compound of nitrogen and hydrogen in water. Version chapter 29psmammonia awareness revision no. Supplemental risk management program guidance for ammonia refrigeration facilities may 2004 note. Wahlco aqueous ammonia delivery systems use two types of vaporizers to generate ammonia. Water is a very weak acid and hydroxide is a very strong base. Ammonia solutions react exothermically with acids to produce water and ammonium salts, heating or treating with strong bases also causes evolution of gaseous ammonia. Process safety management and risk management plan program.
Anhydrous ammonia in liquid or gaseous form has a very strong attraction to water and moisture which targets bodily fluids such as those in the eyes, nose, mouth, respiratory tract, and perspiration and forms strong concentrations of aqueous ammonia that irritate body tissues and may cause injury. Aloha simulation of aqueous ammonia spills the areal locations of hazardous atmospheres aloha, version 5. The concentration of aqueous ammonia solutions for household use is typically 5% to 10% weight. In operation, aqueous ammonia is pumped into the atomizing nozzle at a fixed pressure. Psm pro is a cloud based software program specifically for the ammonia refrigeration industry for compliance with osha 1910. Aqua ammonia is also known as ammonia solution, ammonium hydroxide, ammonia water, ammonical liquor, ammonia liquor, aqueous ammonia, or simply ammonia tccs aqua ammonia is a clear, colorless liquid with a strong pungent ammonia odor. Ammonium hydroxide, 25 percent solution, ammonia solution, fcc, strong ammonia solution, nf, boric acid, 2 percent wv. Operating cost for co2 capture process using aqueous ammonia.
Standard interpretations occupational safety and health. As of 2016, risk management professionals has be an active supporter for the international institute of ammonia refrigeration. Guidance for facilities on risk management programs rmp. Ammonium hydroxide, also known as ammonia water, ammonia solution, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or inaccurately ammonia, is a solution of ammonia in water. Osha 3430 slides for chemical psm inspector training dated april 2010 from the osha training institute retreived from foia by garden city ammonia program on 11. Ammonia water, aqueous ammonia, household ammonia, ammonium hydrate, ammonium hydroxide stcc. We invite you to learn more about them and the benefits of becoming an asti sponsor. Aloha was jointly developed by the national oceanic and atmospheric administration noaa and the u. Service contracts are typically billed monthly so you wont be surprised by any large expenses when an infrequent compliance task is required. Process safety management of highly hazardous chemicals and. Ammonia refrigeration processes will usually not be eligible for this program level because they are covered by osha psm. Airgas specialty products, an air liquide company, is a leading supplier of industrial ammonia and diesel exhaust fluid def. The purpose of this rmppsm manual is to assist with the prevention of accidental releases of toxic and flammable substances that can cause harm to the public, facility employees, and to the environment. For all your ammonia and diesel exhaust fluid needs theres airgas specialty products.